Ghaleh-khargushi rhyodacite and Gorid andesite from Iran: characterization,uses, and durability     

Ahmad Zalooli  David Martín Freire-Lista  Mashalah Khamehchiyan  Mohammad Reza Nikudel  Rafael Fort  Shahram Ghasemi 《Environmental Earth Sciences》2018,77(8):315

Durability of building stones is an important issue in sustainable development. Crystallization of soluble salts is recognized as one of the most destructive weathering agents of building stones. For this reason, durability of Ghaleh-khargushi rhyodacite and Gorid andesite from Iran was investigated against sodium sulfate crystallization aging test. Petrographic and physico-mechanical properties and pore size distribution of these stones were examined before and after the aging test. The characteristics of the microcracks were quantified with fluorescence-impregnated thin sections. Durability and physico-mechanical characteristics of Ghaleh-khargushi rhyodacite are mainly influenced by preferentially oriented preexisting microcracks. Stress induced by salt crystallization led to the widening of preexisting microcracks in Ghaleh-khargushi rhyodacite, as confirmed by the pore size distributions before and after the aging test. The preexisting microcracks of Gorid andesite were attributed to the mechanical stress induced by contraction of lava during cooling. The number of transcrystalline microcracks was significantly increased after the aging test. The degree of plagioclase microcracking was proportional to its size. Durability of the studied stones depends on initial physico-mechanical properties, pore size distribution, and orientation of microcracks. Initial effective porosity is found to be a good indicator of the stones’ durability. Salt crystallization resulted in an increase in the effective porosity with a parallel decrease in the wave velocities. Surface microroughness parameters increased with the development of salt crystallization-induced microcracking. Gorid andesite showed higher quality and durability than Ghaleh-khargushi rhyodacite.  相似文献   

Assessment of the acid drainage neutralization capacity and the toxic metals lixiviation of tailing from Guanajuato mining district,Mexico   总被引：1，自引：0，他引：1  

María Elena García-Arreola  Luisa María Flores-Vélez  Marcos Loredo-Tovías  Alfredo Aguillón-Robles  Rubén Alfonso López-Doncel  Irene Cano-Rodríguez  Sonia Hortensia Soriano-Pérez 《Environmental Earth Sciences》2018,77(9):355

In Mexico, many environmental problems are generated by large mining activities taking place in several mining districts. These mining activities produce great quantities of residues; large majorities of these have high sulfur content, which could generate acid drainage due to their interaction with the oxygen in the environment. The study area was located in the Mining District of Guanajuato, Mexico with abandoned tailings generated mainly by the gold and silver production. Two areas, called as Monte de San Nicolás (SN) and Peregrina (P) were selected for this study. The results study shows that there was no risk of production of acid drainage, since these tailings contained high amount of carbonates, which neutralized the generation of acidity and consequently decreased the possibility of leaching of some elements. However, not all elements leach in acid pH, as arsenic bound to oxyhydroxides, which is in a basic environment and its increased release by increasing the pH.  相似文献   

An orthotropic interface damage model for simulating drying processes in soils     

Osvaldo Manzoli  Marcelo Sánchez  Michael Maedo  Jumanah Hajjat  Leonardo J. N. Guimarães 《Acta Geotechnica》2018,13(5):1171-1186

The study of drying process in soils has received an increased attention in the last few years. This is very complex phenomenon that generally leads to the formation and propagation of desiccation cracks in the soil mass. In recent engineering applications, high aspect ratio elements have proved to be well suited to tackle this type of problem using finite elements. However, the modeling of interfaces between materials with orthotropic properties that generally exist in this type of problem using standard (isotropic) constitutive model is very complex and challenging in terms of the mesh generation, leading to very fine meshes that are intensive CPU demanding. A novel orthotropic interface mechanical model based on damage mechanics and capable of dealing with interfaces between materials in which the strength depends on the direction of analysis is proposed in this paper. The complete mathematical formulation is presented together with the algorithm suggested for its numerical implementation. Some simple yet challenging synthetic benchmarks are analyzed to explore the model capabilities. Laboratory tests using different textures at the contact surface between materials were conducted to evaluate the strengths of the interface in different directions. These experiments were then used to validate the proposed model. Finally, the approach is applied to simulate an actual desiccation test involving an orthotropic contact surface. In all the application cases the performance of the model was very satisfactory.  相似文献   

Toxic metals in a highly urbanized industry-impacted estuary (Bahia Blanca Estuary,Argentina): spatio-temporal analysis based on GIS     

Melisa Daiana Fernández Severini  María Elizabeth Carbone  Diana Mariel Villagran  Jorge Eduardo Marcovecchio 《Environmental Earth Sciences》2018,77(10):393

Cadmium, chromium, nickel, and lead were evaluated in the particulate fraction at one of the most industrialized estuaries at the Southwestern Atlantic Ocean, through Geographic Information System (GIS). Concentrations were analyzed at 21 stations during 2008–2010. The highest metal concentrations (Cd: 8,9; Cr: 256,49; Ni: 27,02; Pb: 78,43 µg g^??1 d. w.) were recorded at the stations located near industrial and urban discharges situated along the estuary. In addition, Pb presented a different seasonal and spatial behavior in comparison with Cd, Cr and Ni. Winter and spring presented the higher concentrations of Pb, and the inner stations presented the higher values. The estuary is considered a moderate to strongly polluted and significantly polluted according to the Index of geoaccumulation (I_geo) and the Enrichment Factor of Cd, respectively. The Multidimensional Scaling plot showed three groups of stations: the inner, associated to low levels of metals (G1), middle stations (G2) with intermediate levels and the outer (G3) with the highest ones. In addition, this work reveals the usefulness of the GIS-mapping techniques in the distribution of pollutants along an estuarine environment and the environmental quality assessment of estuarine systems.  相似文献   

Bioaccumulation of heavy metals in <Emphasis Type="Italic">Limnobium laevigatum</Emphasis> and <Emphasis Type="Italic">Ludwigia peploides</Emphasis>: their phytoremediation potential in water contaminated with heavy metals     

M. Rocío Fernández San Juan  Carolina B. Albornoz  Karen Larsen  Roberto Najle 《Environmental Earth Sciences》2018,77(11):404

Contamination with heavy metals in surface and groundwater is a threat to human health and ecosystems. Due to this, the need arises to remediate water polluted through ecological and profitable technologies, such as phytoremediation. The objective of the work was to evaluate the concentration of lead (Pb) and zinc (Zn) in the floating macrophytes Limnobium laevigatum and Ludwigia peploides, after being exposed to contaminated water experimentally. In this way to be able to determine if these plants have mechanisms that allow them to accumulate the metals in the roots and to perform the translocation of these to different vegetative organs, L. laevigatum and L. peploides were placed in solutions contaminated with Pb ([Pb]?=?5 mg/l) and Zn ([Zn]?=?20 mg/l). The concentrations of metals in water, root and leaf samples were evaluated as a function of time (0, 1, 2 and 4 days). The determination of the metals was performed by the atomic absorption spectrophotometry technique. After 4 days of exposure to Pb and Zn, the plants showed high metal removal efficiencies of water, more to 70% in all cases. Pb was accumulated fundamentally by roots, while Zn was accumulated more in the leaves. In addition, the bioconcentration and translocation factors for each metal were calculated.  相似文献   

Characterization and rehabilitation of the “Porta Férrea” stone materials,University of Coimbra,Portugal     

Lídia Catarino  Francisco P. S. C. Gil  Mário Quinta-Ferreira  Fernando Marques 《Environmental Earth Sciences》2018,77(11):416

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An adjoint-based optimization method for gas production in shale reservoirs     

Antonio A. Novotny  Márcio A. Murad  Sidarta A. Lima 《Acta Geotechnica》2018,13(4):833-852

In this work, we consider a new model for flow in a multiporosity shale gas reservoir constructed within the framework of an upscaling procedure where hydraulic fractures are treated as (\(n-1\)) interfaces (\(n=2,3\)). Within this framework, the hydrodynamics is governed by a new pressure equation in the shale matrix which is treated as a homogenized porous medium composed of organic matter (kerogen aggregates with nanopores) and inorganic impermeable solid (clay, calcite, quartz) separated from each other by a network of interparticle pores of micrometer size. The solution of the pressure equation is strongly influenced by the constitutive response of the retardation parameter and effective hydraulic conductivity where the former incorporates gas adsorption/desorption in the nanopores of the kerogen. By focusing our analyses on this nonlinear diffusion equation in the domain occupied by the shale matrix, an optimization strategy seated on the adjoint sensitivity method is developed to minimize a cost functional related to gas production and net present value in a single hydraulic fracture. The gradient of the objective functional computed with the adjoint formulation is explored to update the controlled pressure drop aiming to optimize production in a given window of time. The combination of the direct approach and gradient-based optimization using the adjoint formulation leads to the construction of optimal production scenarios under controlled pressure decline in the well. Numerical simulations illustrate the potential of the methodology proposed herein in optimizing gas production.  相似文献   

Bioerosion and encrustation rates in recent mollusk death assemblages on a supratidal siliciclastic setting,Playa Norte,Veracruz State,Mexico     

Catalina Gómez-Espinosa  F. Raúl Gío-Argáez  Ester A. Farinati  Salvador Aliotta  Sergio Adrian Salgado-Souto 《Arabian Journal of Geosciences》2018,11(8):188

This study presents both qualitative and quantitative data regarding marine mollusk (gastropods and bivalves) shell bioerosion and encrustation based on death assemblages obtained from a recent supratidal environment in Playa Norte, Veracruz State. The objectives of this study were to assess the nature of bioerosion and encrustation processes and to investigate the role of these taphonomic features contributing to the deterioration of natural shell accumulations within a tropical siliciclastic tidal environment. The assemblage comprises 31 species: 13 gastropods and 18 bivalves. The bioerosion and encrustation degrees were low to moderate for both types. The most abundant traces were predatory gastropod structures (Oichnus paraboloides and O. simplex), whereas sponge borings (Entobia isp.), polychaete dwellings (Caulostrepsis taeniola), and echinoid raspings (Gnatichnus isp.) were less frequent. The encrusting organisms include polychaete serpulids, bryozoans, and rare foraminifers (Homotrema rubrum). Because of the low bioerosion and encrustation degrees occurring in this area, accumulation is expected to predominate over biotic destruction. As deposition conditions (richly fossiliferous carbonate sandstone beds) were similar to those prevailing in the Tuxpan Formation during the Miocene (Langhian), it is suggested that this study provides an equivalent reference to interpret mollusk fossil assemblages located in this site.  相似文献   

Exploratory Factor Analysis of Wireline Logs Using a Float-Encoded Genetic Algorithm     

Norbert Péter Szabó  Mihály Dobróka 《Mathematical Geosciences》2018,50(3):317-335

In the paper, a novel inversion approach is used for the solution of the problem of factor analysis. The float-encoded genetic algorithm as a global optimization method is implemented to extract factor variables using open-hole logging data. The suggested statistical workflow is used to give a reliable estimate for not only the factors but also the related petrophysical properties in hydrocarbon formations. In the first step, the factor loadings and scores are estimated by Jöreskog’s fast approximate method, which are gradually improved by the genetic algorithm. The forward problem is solved to calculate wireline logs directly from the factor scores. In each generation, the observed and calculated well logs are compared to update the factor population. During the genetic algorithm run, the average fitness of factor populations is maximized to give the best fit between the observed and theoretical data. By using the empirical relation between the first factor and formation shaliness, the shale volume is estimated along the borehole. Permeability as a derived quantity also correlates with the first factor, which allows its determination from an independent source. The estimation results agree well with those of independent deterministic modeling and core measurements. Case studies from Hungary and the USA demonstrate the feasibility of the global optimization based factor analysis, which provides a useful tool for improved reservoir characterization.  相似文献   

Deep seismic exploration of the Iberian Microplate     

Juvenal Andres  David Marti  Ignacio Marzan  Imma Palomeras  Puy Ayarz  Fernando Simancas  DavidMartinez-Poyatos  Antonio Azor  Francisco Gonzalez-Lodeiro?  Jordi Diaz  Ramon Carbonel 《《地质学报》英文版》2018,92(Z1):11-11

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